This study measured the ignition limits of methane-air, propane-air, ethylene-air, and hydrogen-air mixture gases by discharge spark of D.C. power resistive circuit. The used experimental device is the IEC type spark ignition test apparatus, it consists of explosion chamber and supply -exhaust system of mixture gas. Mixture gases (methane-air, propane-air, ethylene-air, and hydrogen-air) were put into explosion chamber of IEC type spark ignition test apparatus, then it was confirmed whether ignition was made by 3,200 times of discharge spark between tungsten electrode and cadmium electrode. The ignition limits were found by increasing or decreasing the value of current. For the exact experiment, the ignition sensitivity was calibrated before and after the experiment in each condition. The ignition limits were found by changing the value of concentration of each gas-air mixture in D.C. 24 [V] resistive circuit. As the result of experiment, it was found that the minimum ignition limit currents exist at the value of methane-air 8.3 [$Vol\%$], propane-air 5.25[$Vol\%$], ethylene-air 7.8 [$Vol\%$], and hydrogen-air 21[$Vol\%$] mixture gases. For each the minimum ignition concentration of gases, the relationships between voltage and minimum ignition current were found. The results are as follows. - The minimum ignition limits are decreasing in the order of methane, propane, ethylene, and hydrogen. - The value of ignition current is inversely proportional to the value of source voltage. - The minimum ignition limit currents increase sharply at more than 2 [A]. The reason is caused by overheating the electrode.