Flame oscillation phenomena in a co-flow diffusion flame was experimentally studied with periodic fuel supply using a solenoid valve. The degree of excitation was controlled by changing the volume flux of fuel passing through the valve. Flame oscillation frequencies were measured utilizing a photodiode, a spectrum analyzer, video and high speed movies. Laser planar visualization was employed to study the correlation between the flame oscillation and the toroidal vortices. Observed are three regimes of flame oscillation, where the oscillation frequencies are for the multiples of excitation, the excitation itself and the flame natural oscillation. Both periods of natural oscillation and of excitation induced oscillation exist over one cycle of the excitation in the frequency multiplied regime. It is considered as an effect of balancing the influence of buoyancy driven vortex with that of excitation induced vortex near the excitation rate of 0.2. Flame shapes are become monotonous as increasing the excitation frequency to the range of over two fold of the natural oscillation. The flame oscillation can be modulated to the frequency of either multiples of excitation or excitation itself under certain conditions. This implies that the flame oscillation could be modulated to avoid the resonance frequency of the combustor, and shows the possibility of active control of the flame oscillation.