The phusical optics approximation to an E-polarized diffraction by a composite wedge provides its diffraction coefficients in terms of finite series of cotangent functions. In this paper, its diffraction coefficients inside the dielectric part are extended to become the exact solution to the perfectly conducting wedge as its relative dielectric constant increases to infinite or decreases to 1. It is assured that the extended diffraction coefficients satisfy the boundary condition at th econducting interface and become zero in the artificially complementary region of the composite wedge.