An electro-optic polymer digital optical switch with a coupling region modified for optimum coupling is designed and demonstrated. Its branch waveguide is fabricated by reactive ion etching. Then, the modified coupling region is adiabatically introduced along the propagation direction from the branching point of the two waveguides, and it is implemented by photobleaching after the device fabrication. The structure of the modified coupling region and its refractive index profiles are designed to optimize and mode coupling in the Y-branch waveguide. Therefore, the switching performance of the device was shown to be enhanced with a fixed device length. The measured drive voltage is reduced by more than 30 percents, and the crosstalk is also improved by about 4~6 dB.