A new method is presented to determine two fundamental acoustic quantities of sound-absorbing materials such as characteristic impedance and propagation constant. In this study, the surface acoustic impedances of sound-absorbing materials are measured using the impedance tube and the anechoic chamber to determine the above acoustic quantities. The measured results are given for two typical sound-absorbing materials(glass wool and urethane foam) int the frequency range between 150 and 1, 600 Hz. The results are verified by other two known methods, which are Smith & Parrott method and Utsuno et al. method. The absorption coefficients calculated from the empirical models(Miki model for glass wool and Jung model for urethane foam) and two quantities by present method are in good agreement with the measured values.