Since, human error is a major factor contributing to disaster during start-up of operation in Boiler plant. it is necessary to develop an automation system which prevent mode of operation that are known to be dangerous and to bring a loss of energy. The aim of this study is to suggest a model for the computer-aided synthesis of operation sequence as a part of automation system for start-up operation. Synthesis is accomplished by the formation of a hierarchical network of goals which decide sequence of operations. Hierarchical Network is formed by using method which upper goals ( i.e. upper operation al situation) are classified by the function of themselves into lower goals (i.e. lower operational situation). Knowledge for deciding operation sequence is generated by putting In order the knowledge of hazard operation and energy management.