For the labor-saving cultivation of barley in rice-barley double cropping system in paddy field, a series of expriments on the effect of rice straw application were carried out at the National Yeongnam Agricultural Experiment Station from 1992 to 1993. The affection of phenol compounds released from fresh rice straw could be lessened when seeded under rice straw in the soil and that made emergence rate increase by 11％, compared with that on application on the rice straw. Although utilization of rice straw as an organic material caused the poor growth of barley in early stage, it could be enhanced the culm breaking strength. On this reason, affected by rice straw, grain yield was increased from 8％ in common barley and up to 20％ in malting barley. The more nitrogen, CaO$_2$2 and SiO$_2$ applied, the more decomposition of rice straw accelerated from 2％ to 6.9％. On the application of rice straw as an organic material in malting barely cultivation, the content of crude protein was decreased while 1,000-grain-weight and grain assortment was increased.