This paper is concerned with defects detection and evaluation of heat affected zone (HAZ) in austenitic stainless steel type 304 by ultrasonic wave and neural network. In experiment, the reflected ultrasonic defect signals from artificial defects (side hole, vertical hole, notch) of HAZ appears as beam distance of prove-defect, distance of probe-surface, depth of defect-surface on CRT. For defect classification simulation, neural network system was organized using total results of ultrasonic experiment. The organized neural network system was learned with the accuracy of 99%. Also it could be classified with the accuracy of 80% in side hole, and 100% in vertical hole, 90% in notch about ultrasonic pattern recognition. Simulation results of neural network agree fairly well with results of ultrasonic experiment. Thus were think that the constructed system (ultrasonic wave - neural network) in this work is useful for defects dection and classification such as holes and notches in HAZ of austenitic stainless steel 304.