In this study, a total of 10 volatile organic compounds (VOCs) including BTEX were determined in the inside and outside of a highway thnnel in order to evaluate the emission profile of automobile exhaust with respect to the concentrations, relative ratio and correlation coefficient of target analytes. In addition to VOCs, CO $CO_2 and NO_2$ were measured simultaneously. The results of this study indicated that the most abundant compound was toluene followed by benzene and m+p-xylenes, and the correlation coefficients between VOCs except styrene were higher than 0.96. The concentration ratio of toluene, ethylbenzene, xylenes with respect to benzene measured in the inside of tunnel was 1.5, 0.13, 0.74, respectively. Such ratios were found to be very similar to those measured in tunnels in the USA.