This experiment carried out in order to investigate the effect of the chemical activators for acceleration of hydration the system of Fly ash-Cao The paste was consisted of 80wt% Fly ash and 20wt% CaO with 1. 3. 5wt% of 4 activators(N{{{{ alpha _2 }}S{{{{ OMICRON _4 }}, CaC{{{{ {l }_{2 } }}, NaOH, Ca(N{{{{ OMICRON _3 {)}_{2 } }} and W/S ratio of 0.42 After curing for 1, 3, 7, 14, 28 days the paste hydration was characterized by the measurement of compressive strength XRD analysis SEM observation the combined water and the reaction amount of Ca(OH)2 determination. As a result of this ex-periment all of the system which involved Na2SO4 or NaOH had a god compressive strength. In the case of 7 days curing a system which added CaCl2 showed the highest compressive strength among all especially NaOH system showed a high increase in strength as a dosage of it increased. Hydration products were different according to activatores added. Only C-S-H was observed in NaOH system. As the reaction amount of Ca(OH)2 and combined water were increased the compressive strength increased. There were few differences in the comparision of strength between ignited loss 3.1% and loss 9.3% of fly ash.