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CARBON ISOTOPE ANALYSES OF INDIVIDUAL HYDROCARBON MOLECULES IN BITUMINOUS COAL, OIL SHALE, AND MURCHISON METEORITE
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  • CARBON ISOTOPE ANALYSES OF INDIVIDUAL HYDROCARBON MOLECULES IN BITUMINOUS COAL, OIL SHALE, AND MURCHISON METEORITE
  • CARBON ISOTOPE ANALYSES OF INDIVIDUAL HYDROCARBON MOLECULES IN BITUMINOUS COAL, OIL SHALE, AND MURCHISON METEORITE
저자명
Kim. Kyoung-Sook,Yang. Jong-Mann
간행물명
韓國宇宙科學會誌
권/호정보
1998년|15권 1호|pp.163-174 (12 pages)
발행정보
한국우주과학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

To study the origin of organic matter in meteorite, terrestrial rocks which contain or-ganic compounds similar to the ones found in carbonaceous chondrites are studied and compared with Muchison meteorite. Hydrocarbon molecules were extracted by benzene and methanol from bituminous coal and oil shale and the extracts were partitioned into aliphatic, aromatic, and polar fractions by silica gel column chromatography. Carbon isotopic ratios in each fractions were analysed by GC-C-IRMS. Molec-ular compound identifications were carried by GC-MS Engine. Bituminous coal and oil shale show the organic compound composition similar to that of meteorite. Oil shale has a wide range of ${delta}^{13}C,-20.1%_0~-54.4%_0$ compared to bituminous coal, $-25.2%_0~34.3%_0$. Delta values of several molecular compounds in two terrestrial samples are different. They show several distinct distributions in isotopic ratios compared to those of meteorite; Murchison meteorite has a range of ${delta}^13C;from;-13%_0;to;+30%_0$. These results provide interpretation for the source and the formation condition of each rock, in particular alteration and migration processes of organic matter. Especially, they show an important clue whether some hydrocarbon molecules observed in meteorite are indigenous or not.