A theoretical study of three-dimensional unsteady compressible non-reacting flow inside double flow of monolith catalytic converter system attached to 6-cylinder engine was performed for the achievement of performance improvement, reduction of light-off time, and longer service life by improving the flow distribution of pulsating exhaust gases. The differences between unsteady and steady-state flow were evaluated through the numerical computations. To obtains the boundary conditions to a numerical analysis, one dimensional non-steady gas dynamic calculation was also performed by using the method of characteristics in intake and exhaust system. Studies indicate that unsteady representation is necessary because pulsation of gas velocity may affect gas flow uniformity within the monolith. The simulation results also show that the level of flow maldistribution in the monolith heavily depends on curvature and angles of separation streamline of mixing pipe that homogenizes the exhaust gas from individual cylinders. It is also found that on dual flow converter systems, there is severe interactions of each pulsating exhaust gas flow and the length of mixing pipe and junction geometry influence greatly on the degree of flow distribution.