Ni-W alloys containing 10 to 50wt% W were prepared by electrodeposition. Tungsten content in the alloy increased with current density. X-ray diffraction analysis revealed that the alloy was crystalline phase when deposited at current densities lower than 50mA/${cm}^2$. Their crystal structure transformed to amorphous at higher current densities. In terms of tungsten content, the crystal -+ amorphous transition occurred at 40-46wt% which was identified by the 3 fold increase in the width of a diffraction peak. The lattice parameter of crystalline phase increased with W upto 40wt% which is higher than the solubility limit of W (about 30wt%) in Ni. Therefore, the alloys are considered to be Ni solid solution supersaturated with W. The amorphous Ni-W alloys were recrystallized by annealing them at temperatures over $400^{circ}C$. This was evidenced by the appearance a strong [ 11 11 annealing texture. The supersaturated W was precipitated during the annealing at over $800^{circ}C$. The current-density dependence of W content and crystallinity was utilized to produce alternating layers of crystalline (30wt% W) and amorphous (50wt%) phases which may exhibit unique mechanical and corrosion properties.