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Na$_2$B$_4$O$_7$-KCl-LiCl 혼합용융욕에서 TiAl계 금속간 화합물의 전해붕화처리
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  • Na$_2$B$_4$O$_7$-KCl-LiCl 혼합용융욕에서 TiAl계 금속간 화합물의 전해붕화처리
저자명
이두환,김익범,이주호,김수식
간행물명
한국표면공학회지
권/호정보
1998년|31권 6호|pp.359-370 (12 pages)
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한국표면공학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

TiAl-based intermetallic compounds were electro-bornizel in the mixture of $Na_2B_4O_7$, KCL and LiCl in the termetature rage between 850 and $1000^{circ}C$for various times (1-5 hours)under the fixed current density of 0.5 A/$cm^2$. The optimized composition of electrolyte in this work was decided to be 76.9 wt% $Na_2B_4O_7$-19.2 wt.%(0.7KCl-0.3LiCl) -3.9 wt.% al. The samples with boronized layer were investigated by SEM, XRD and EDS. The surface micro-hardness of boronized TiAl was also evaluated using Micro Vickers Hardness Tester. The sample, boronized at $900^{circ}C$ for 4 hours in the above composition of electrolyte under the current density of 0.5 A/$ extrm{cm}^2$, has about 36$mu extrm{m}$ think layer on the surface, and its surface micro-hardness was measured to be 1263 Hv. From the results of SEM, XRD and EDS, the layer consisted of $TiB_2$ sublayer and Al-oxide sub layer. Al-depleted layer below the Al-oxide sudlayer was also detected. The activation energy for formation of boronized layer in this study was calculated as 178 Kcal/moleK.