In this paper, we obtained the monodomain alignment of nematic liquid Crystal(NLC) in the cell fabricated by transcription alignment method on polyimide(PI) surface with side chain. It is considered that the LC alignment produced by the transcription alignment method is attributed to a memory effect of the NLC on PI surfaces. Also we observed that the generated pretilt angle of NLC is about $3.7^{circ}$ with transcription alignment on PI surface. Next, we measured that the voltage-transmittance characteristics of transcription-aligned TN-LCD are almost same compared to rubbing-aligned TN-LCD. Also, we measured that the curve of transcription-aligned TN-LCD is less sharp than that of the rubbing-aligend TN-LCD in the decay time characteristics. It is considered that the response time characteristics of transcription-aligned TN-LCD are attributed to the weak anchoring strength between the LC molecules and the polymer surface.