The vaporization process of liquid oxygen(LOX) at high pressure environment is numerically investigated. The present vaporization model can account for the high-pressure effects such as ambient gas solubility, real gas behavior and variable properties. The predicted phase-equilibrium compositions for $N_2$/$H_2$ and $O_2$/He system are well agreed with experimental data. The LOX vaporization characteristics is parametrically studied for wide range of the operating conditions encountered in the high-pressure combustion process of liquid rocket engine