An experimental chamber was fabricated to observe the gas diffusion behavior of leak gas from underground city-gas pipeline. It was made of acryl so that feeding of gas and the measuring points of the gas could be varied in each experiment. The MOS sensors were used to measure the concentrations of leak gas. The soil media such as the Jumunjin standard sand and the granite weathered soil were used to measure the gas diffusion and the change of leak gas concentrations was measured with time for various gas flow rate. As the distance between the leak point of gas and the measuring point of MOS sensor decreases, or the leak rate increases, the detection time of gas at a measuring points decreases and the gas concentration increases quickly and the concentration of the gas at steady state also increases. As the density of granite weathered soil is higher than that of Jumunjin standard sand for compaction, the detection time of leak gas in the granite weathered soil was longer than that in the Jumunjin standard soil. The leak gas concentrations in the granite weathered soil were lower than those in the Jumunjin standard sand at the beginning of gas leaking from a pipe, but inverse phenomenon was occured at steady state.