Ultrafast carrier dynamics of LT-GaAs semiconductors was investigated by using time-resolved photoreflectance spectroscopy. We can see that decay dynamics of photoreflectance generated by carriers depends strongly on the excitation wavelength due to the structure distortion of LT-GaAs semiconductors. Ultrafast trapping of excited carriers into deep trap states gives rise to transient photoreflectance decays with a lifetime shorter than 1 ps. Also, the long-lived photoreflectance is attributed to the carriers trapped deeply at point defects. fects.