Hydrocarbon emission from spark ignition engines deeply relates with fuel evaporation mechanism. Therefore, fuel evaporation on the back of the intake valve is very important to understand fuel evaporation mechanism during engine warm up period. Intake valve heat transfer model was build up to estimate the amount of fuel evaporation on the intake valve back . Intake valve temperature was measured intake valve temperature is increased rapidly during few seconds right after engine start up and it takes an important role on fuel evaporation. The liquid fuel evaporation rate on the intake valve back proportionally increases as valve temperature increases, however its contribution slightly decreases as intake port wall temperature increases. The fuel evaporation rate on the valve back is about 40∼60% during engine warm-up period and it becomes about 20∼30% as intake port wall temperature increases. The estimation model also makes possible model also makes possible to review the effect of valve design parameters such as the valve mass and seat area on fuel evaporation rate through intake valve heat transfer.