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Effects of $Nb_2O_5$, and Oxygen Potential on Sintering Behavior of $UO_2$ Fuel Pellets
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  • Effects of $Nb_2O_5$, and Oxygen Potential on Sintering Behavior of $UO_2$ Fuel Pellets
  • Effects of $Nb_2O_5$, and Oxygen Potential on Sintering Behavior of $UO_2$ Fuel Pellets
저자명
Song. Kun-Woo,Kim. Keon-Sik,Kang. Ki-Won,Jung. Youn-Ho
간행물명
Journal of the Korean Nuclear Society
권/호정보
1999년|31권 3호|pp.335-343 (9 pages)
발행정보
한국원자력학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The effects of N $b_2$ $O_{5}$ and oxygen potential on the densification and grain growth of U $O_2$ fuel have been investigated.0.3 wt% N $b_2$ $O_{5}$ -doped U $O_2$fuel pellets were sintered at 1$700^{circ}C$ for 4 hours in sintering atmospheres which have various ratios of $H_2O$ to $H_2$ gas. Compared with those of undoped U $O_2$ pellets, the sintered density and grain size of the 0.3 wt% N $b_2$ $O_{5}$ -doped U $O_2$ pellet increase under the $H_2O$/ $H_2$ gas ratio of 5.0$ imes$10$^{-3}$ to 1.0$ imes$10$^{-2}$ and under the $H_2O$/ $H_2$gas ratio of 5.0$ imes$10$^{-3}$ to $1.5 imes$10$^{-2}$ , respectively. The sintering of U $O_2$fuel pellets containing 0.1 wt% to 0.5 wt% N $b_2$ $O_{5}$ was carried out at 168$0^{circ}C$ for 4 hours. The enhancing effect of N $b_2$ $O_{5}$ on the sintered density and grain size becomes larger as the N $b_2$ $O_{5}$ content increases. The solubility limit of N $b_2$ $O_{5}$ in U $O_{2}$ seems to be between 0.3 wt% and 0.5 wt%, and beyond the solubility limit the second phase whose composition corresponds near to N $b_2$U $O_{6}$ is precipitated on grain boundary. The enhancement of densification and grain growth in U $O_2$ is attributed to the increased concentration of a uranium vacancy which is formed by the interstitial N $b^{4+}$ ion in the U $O_2$ lattice.