KOMPSAT is a three-axis stabilized light weight satellite, and one of the main mission objectives of the KOMPSAT is to conduct scientific and technological analysis in the areas of high resolution imaging and ocean color imaging. This kind of mission requires the satellite to roll up to 45 degrees. Bang-bang control for this rolling maneuver may activate the flexible modes, and therefore cause satellite pointing performance degradation. To deal with this problem, the roll attitude control system, especially for the science mode and maneuver mode of the KOMPSAT, is first verified by numerical simulation. And the open-loop control law for roll maneuver is proposed by use of series expansion and optimization. The proposed control law is applied to KOMPSAT to see its effectiveness.