- 백금촉매의 표면반응에 미치는 압력의 영향에 관한 실험 및 이론적 연구
- ㆍ 저자명
- 김형만,Kim. Hyung-Man
- ㆍ 간행물명
- 한국연소학회지
- ㆍ 권/호정보
- 2000년|5권 1호|pp.1-6 (6 pages)
- ㆍ 발행정보
- 한국연소학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Surface reaction occurs at a certain surface temperature when a catalyst is heated up in a reactive mixture. If homogeneous ignition does not occur, a steady state is observed because the heat produced by the surface reaction is balanced with the heat loss caused by convection, conduction and radiation. The present paper treats the effects of pressure on the surface temperature at the steady state. Hydrogen and oxygen are used as reactants and nitrogen as an inert gas. A spherical platinum catalyst of 1.5 mm in diameter is sustained in the chamber with two wires of 0.1 mm in diameter. As results, there exists a maximum steady temperature at a certain relative hydrogen concentration which increases with total pressure. At the steady state, it can be approximated that the heat release is estimated by the mass transfer considering the effect of natural convection. The experimental results are explained qualitatively by the approximation.