On the absorber of absorption chiller/heater, LiBr solution at high concentration is sprinkled on a bundle of horizontal tube cooled by cooling water. In this case, the conditions of LiBr solution and cooling water have an influence on heat/mass transfer coefficient in this system. Therefor it is important to find optimal operation conditions of absorption chiller/heater to save energy. Heat and mass transfer coefficient increased with the increase of solution flow rate, and also heat and mass transfer rate increased but overall heat and mass transfer coefficient decreased by increasing the solution concentration within the experimental range. The superheating of the solution resulted in superior heat transfer character to a state of equilibrium from the point of heat flux and overall heat transfer coefficient.