- (65)Pb(${Mg_{1/3}}{Nb_{2/3}}$)$O_3$-(35)$PbTiO_3$의 입자성장과 치밀화에 미치는 과량 PbO의 영향
- ㆍ 저자명
- 이종봉,허태무,이호용,최균,김도연
- ㆍ 간행물명
- 한국세라믹학회지
- ㆍ 권/호정보
- 2000년|37권 7호|pp.673-680 (8 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The effect of excess PbO(0, 1, 2, 4, and 8 mol%) on grain growth and densification of (65)Pb(Mg1/3Nb2/3)O3-(35)PbTiO3 [mol%] ceramics has been investigaetd. With increasing the amount of excess PbO and sintering time, densities of sintered samples decreased gradually. The samples containing less than 1 mol% of PbO showed normal grain growth behavior, however abnormal grain growth was observed to occur in the samples with more than 2 mol% of PbO. In the samples with more than 2 mol% of PbO, the number of abnormal grains decreased and thus the average grain size became smaller with increasing the amount of excess PbO. These results demonstrated that the abnormal grain growth started to occur when a critical amount of excess PbO was added to a (65)Pb(Mg1/3Nb2/3)O3-(35)PbTiO3 sample. Since PMN-PT grains in a liquid matrix were angular, the observed abnormal grain growth was explained to proceed through the two dimensional nucleation process.