This study was investigated to the recovery of alumina from the first calcined waste pottery using alkaline sintering. This study was based on calcination result of a commercial ${alpha}-Al2_O_3$ with NaOH powder. $NaAlO_2$ was formed by calcination of ${alpha}-Al_2O_3$ with NaOH and conversion of $NaAlO_2$ from ${alpha}-Al_2O_3$ was 91.4% at calcination condition ; weight ritio of $NaOH/{alpha}-Al2_O_3$ 1.5, $800^{circ}C$, and 90min. The first calcined waste porrery from the manufacturing Procedure of H Ltd. was grinded to 170/270mesh by a ball mill and calcined over $500^{circ}C$ with NaOH powder. The calcined sample was dissolved in $25^{circ}C$ water and sodiumaluminosilicate solid was formed. After filtration, the contained aluminum was leached out by dissolving sodiumaluminosilicate solid in 1N HCl. We estimated the efficiency of Al extraction from waste pottery by ICP analysis and NaOH was added to the filtrate and then aluminum compound was precipitated with $Al(OH)_3$ and recovered. The investigation was carried out with the variables ; the calcination temperature($500-900^{circ}C$), the calcination time(30~90min), and the weight ratio of NaOH/waste pottery(0.5~1.5). The treatment efficiency of the waste pottery and the recovery of Al as 97.9%, 91.9% were obtained under the optimum conditions as followed ; the weight ratio of NaOH/waste pottery was 1.5 and the calcination conditions were $900^{circ}C$ and 60min.