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Interactions of methylated $eta$-cyclodextrin and hydrophobically modified alkali-soluble emulsion (HASE) polymers: a rheological study
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  • Interactions of methylated $eta$-cyclodextrin and hydrophobically modified alkali-soluble emulsion (HASE) polymers: a rheological study
  • Interactions of methylated $eta$-cyclodextrin and hydrophobically modified alkali-soluble emulsion (HASE) polymers: a rheological study
저자명
Gupta. R.K.,Tam. K.C.,Ong. S.H.,Jenkins. R.D.
간행물명
Korea-Australia rheology journal
권/호정보
2000년|12권 2호|pp.93-100 (8 pages)
발행정보
한국유변학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The interactions between methylated $eta$-cyclodextrin (CD) and hydrophobically modified alkali-soluble associative polymers (HASE) were examined by a rheological technique. The effect of "capping" of hydrophobes by methylated $eta$-cyclodextrin on the viscosity and modulus was evaluated. Model HASE polymers with $C_1$to $C_{20}$ alkyl hydrophobic groups ethoxylated with~10 moles of ethylene-oxide (EO 10) and at concentrations up to 3 wt% were examined. With the addition of methylated $eta$-CD, the steady shear viscosity profiles shift from a Newtonian profile to one that display a shear-thinning characteristic. Significant "capping" of the hydrophobes occurs for HASE polymers with $C_{l2}$, $C_{16}$ and $C_{20}$ hydrophobes as reflected by the large reduction in the viscosity. However, the steady shear viscosity remains constant when the concentration of $eta$-CD exceeds 1 wt%, suggesting that $eta$-CD is not able to fully encapsulate the hydrophobes of the HASE polymer. The temperature variation plots indicate that the activation energy of the HASE-EO10-$C_{20}$ system and $eta$-CD is dependent on the magnitude of the applied shear stress. These results further reinforce the hypothesis that $eta$-CD is not able to completely remove all the hydrophobic associations.phobic associations.