- 활성탄소계 섬유포 전극을 이용한 전기이중층 커패시터용 유기 전해액의 제조
- ㆍ 저자명
- 강안수
- ㆍ 간행물명
- 안전경영과학회지
- ㆍ 권/호정보
- 2000년|2권 2호|pp.95-108 (14 pages)
- ㆍ 발행정보
- 대한안전경영과학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Electrochemical charateristics of activated carbon fiber cloth(ACFC) electrode were studied with propylene carbonate(PC), ${gamma}$-butyrolactone(GBL) and N,N-dimethyl-formamide(DMF) as a solvent and tetraethylammoniumtetrafluoroborate(TEABF$_4$), tetraethylammoniumhexafluorophosphate(TEABF$_{6}$), tetrabutylammoniumtetrafluoroborate(TBABF$_4$) and tetrabutylammonium hexafluorophosphate(TBAPF$_6$) as an electrolytes(active material). The concentrations of electrolytes were in the range of 0.2~1.2 N, the volume ratios of PC and DMF as a mixed solvent system, were 90:10, 80:20, 70:30, 60:40, 50:50, and 40:60 vol%. Electrochemical characteristics such as electric conductivity, internal resistance, and electric capacitance of fabricated unit cells were measured after the moisture of activated material was removed with molecular sieve. Electrochemical characteristics were better in mixed solvents system than in mono solvent system. The mono solvent system of 1.0 N electrolyte of GBL/TEABF$_4$ with activated carbon cloth electrodes showed better result but the mixed solvent system with PC and DMF/TEABF$_4$(50:50 vol%) and the concentration of 1.0 N electrolyte showed the best characteristics. Internal resistance was 3.47 $Omega$ and specific capacitance was 19.1 F/g respectively.y.