In this paper we proposed the orthogonal neural network(ONN) to control and identify the unknown controlled system. The proposed ONN used the buffer layer in front of the hidden layer and the hidden layer used the sigmoid function and its derivative a derived RBF that is a derivative of the sigmoid function. In order to verify the property of the proposed, it is examined by simulation results of the Narendra model. Controlled system is composed of ONN and confirmed its usefulness through simulation and experimental results.