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A Study on Local Segmental Motions of Methylene Chain in Poly(Butylene Terephthalate) in Solution Phase
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  • A Study on Local Segmental Motions of Methylene Chain in Poly(Butylene Terephthalate) in Solution Phase
  • A Study on Local Segmental Motions of Methylene Chain in Poly(Butylene Terephthalate) in Solution Phase
저자명
남궁현,오정래,이조웅,NamGung. Hyeon,O. Jeong Rae,Lee. Jo Ung
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2000년|21권 11호|pp.1071-1076 (6 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Temperature dependent data of 13C spin-lattice relaxation times and NOE factors for methylene carbons at 50.3MHz and 125.5 MHz have been used to probe the local chain dynamics of poly(butylene terephthalate) (PBT) in solution phase. The interpretation of the relaxation data for methylene chain carbons in PBT was attempted on the basis of several proposed motional models, among which the DLM model was found to be superior. Analysis based on the DLM model indicated that the motion of the $OCH_2groups$ was more restricted compared with the central methylene carbon, which is consistent with conclusions from solid state experiments reported by other investigators. Librational amplitudes of terminal and central carbon of PBT were estimated to be $29.84^{circ}$ and $32.01^{circ}respectively.$,