Natural convection in a wide-gap horizontal annulus is considered, and the transition of flows and the bifurcation phenomenon are investigated for the fluids with Pr=0.2 and 0.3. At Pr=0.2, a bicellular flow pattern is observed at high Rayleigh number, and the solution is unique. At Pr=0.3, both the steady unicellular and bicellular flows exist above a certain critical Rayleigh number. For the fluids of Pr=0.2, the bicellular flow can be obtained by the impulsive heating of the inner cylinder, but it is not obtained from the zero initial condition for Pr=0.3. Hysteresis phenomena have not been observed. A transition from a bicellular flow to a unicellular flow occurs for Pr=0.3.