The local heat/mass transfer coefficients for arrays of impinging circular air jets on a plane surface are determined by means of the naphthalene sublimation method. Fluid from the spent jets is constrained to flow out of the system in one direction. Therefore, the spent fluid makes a crossflow in the confined space. The present study investigates effects of jet-orifice-plate to impingement-surface spacing and jet Reynolds number. The spanwise- and overall-averaged heat/mass transfer coefficients are obtained by numerical integrating the local heat transfer coefficients. The local maximum heat/mass transfer coefficients move further in the downstream direction due to the increase of crossflow velocity. At the mid-way between adjacent jets, the heat/mass transfer coefficients have a small peak owing to the collision of the adjacent wall jets and are affected strongly by the crossflow. The effect of the crossflow occurs strongly at the small orifice-to-impingement surface distance.