The mathematical processing (unfolding) of pulse height spectra from a scintillation detector helps to calculate the photon fluence rate energy distribution in a measured photon field. The data processing is based on the knowledge of detection system response function and directional dependence respectively. The experimental results of the photon fields measurements in the vicinity of the spent fuel temporary storage and inside the storage hall are presented. The containers Castor 440 are used for temporary storing of the burnt up fuel assemblies in the Czech nuclear power plant Dukovany. A set of periodical measurements was performed in order to get basic information on the time dependence of the photon fields spatial distributions and spectral characteristics in the temporary storage hall and its vicinity. The photon fields were measured by the scintillation system. The obtained photon fields spatial distributions and spectral characteristics present the information on the radiation hazard in the storage.