Spatial distribution of groundwater contaminant concentration has special characteristics such as approximate symmetric profile, for example, in the transversal direction to groundwater flow direction, a certain ratio in directional propagation distances, etc. To obtain a geophysically appropriate semivariogram which is a key factor in estimation of groundwater contaminant concentration at desired locations, these special characteristics should be considered. Specifically, the concepts of symmetry and ratio are considered in this paper. By applying these two concepts, significant improvement of semivariograms, estimation variances, and final estimation results compared with the ones by conventional approaches which usually do not account for symmetry and ratio are shown using field experimental data. AMS Mathematics Subject Classifications : 86A32