In this paper, not only the development of optimizing of friction welding with more reliability and more applicability but also the development of in-process real-time weld quality (such as strength and toughness) evaluation technique by acoustic emission for friction welding of the engine exhaustive valve (SUH3-SUH35 dissimilar steels of 12.3mm, 16mm, 20mm, and 24mm in diameters) were performed, comparing with the other FRW matches of materials such as SUH3 to SUH31, STS303 and SUH3 to STS304. As an important result, the techniques for dissimilar friction welding optimization of engine heat resisting steels SUH3 and SUH35 (12.3mm, 16mm, 20mm, and 24mm) and its real-time weld quality evaluation by AE was developed, considering on both diameter and carbon equivalent effects.