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산화물 수소환원에 의한 W-Ni-Fe 나노복합분말의 합성과 특성
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  • 산화물 수소환원에 의한 W-Ni-Fe 나노복합분말의 합성과 특성
저자명
이창우,윤의식,이재성
간행물명
한국분말야금학회지
권/호정보
2001년|8권 1호|pp.49-54 (6 pages)
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한국분말야금학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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The synthesis and characteristics of W-Ni-Fe nanocomposite powder by hydrogen reduction of ball milled W-Ni-Fe oxide mixture were investigated. The ball milled oxide mixture was prepared by high energy attrition milling of W blue powder, NiO and $Fe_2O_3$ for 1 h. The structure of the oxide mixture was characteristic of nano porous agglomerate composite powder consisting of nanoscale particles and pores which act as effective removal path of water vapor during hydrogen reduction process. The reduction experiment showed that the reduction reaction starts from NiO, followed by $Fe_2O_3$ and finally W oxide. It was also found that during the reduction process rapid alloying of Ni-Fe yielded the formation of $gamma$-Ni-Fe. After reduction at 80$0^{circ}C$ for 1 h, the nano-composite powder of W-4.57Ni-2.34Fe comprising W and $gamma$-Ni-Fe phases was produced, of which grain size was35nm for W and 87 nm for $gamma$-Ni-Fe, respectively. Sinterability of the W heavy alloy nanopowder showing full density and sound microstructure under the condition of 147$0^{circ}C$/20 min is thought to be suitable for raw material for powder injection molding of tungsten heavy alloy.