A series of experiments have been carried out to investigate the effects of non-condensable gas on the direct contact film condensation of vapor mixture under an adiabatic wall condition. The average heat transfer coefficient of the direct contact condensation was obtained at the atmospheric pressure with four main parameters ; air-mass fraction, mixture velocity, film Reynolds number, and the degree of water film subcooling having an influence on the condensation heat transfer coefficient. With the analysis of 88 experiments, a correlation of the average Nusselt number for direct contact film condensation of steam/air mixture at an adiabatic vertical wall was proposed as functions of film Reynolds number, mixture Reynolds number, air mass fraction, and Jacob number. The average heat transfer coefficient for steam/air mixture condensation decreased significantly while air mass fraction increased. The average heat transfer coefficients also decreased as the Jacob number increased, and were scarcely affected by the film Reynolds number below a mixture Reynolds number of about 245,000.