In this paper, the effects of scale formation in engine water jacket upon the thermal durability of engine itself and its component parts were studied. To understand the effect of quality of water, a full load engine endurance test for 50 hours was carried out with not-treated underground water. The followings were found through the tested engine inspection after the endurance test; 1-2 mm thick scale formation in the engine water jacket, valve seat wear, piston top land scuffing, piston pin stick, and cylinder bore scuffing in siamese area. In order to understand the causes of above test results, the heat rejection rate to coolant, the metal surface temperature of combustion chamber, and the oil and exhaust gas temperatures were measured and analyzed. The scale formed in the engine water jacket played a role as thermal insulator. The scale formed in the engine reduced the heat rejection rate to coolant and it caused to increase the metal surface temperature. The reduced heat rejection rate to coolant increased the heat rejection rate to oil and exhaust gas and increased the oil and exhaust gas temperature. Also, the reasons of valve seat wear, piston top land scuffing and cylinder bore scuffing, and piston pin stick quantitatively analyzed in this paper.