Nitrogen oxides(NOx) and smoke emissions of diesel engine are regarded as a source of air pollution, and there is a global trend to enforce more stringent regulations on these exhaust gas emissions. However, the trade-off relation of NOx and smoke is a main obstacle to reduce both of them simultaneously. In this paper, experiments were conducted with an oxygenated fuel(diethyl ether) as an effective way to improve the trade-off relation of NOx and smoke. Exhaust emissions of diesel fuels with DEE were influenced by the additive content of DEE and the injection timing. Especially, DEE effected more at the high engine speed and load than at the low engine speed and load. Diesel fuel blended with DEE 10% was a desirable blend for the simultaneous reduction of NOx and smoke.