In this study the leakage current measurement method based on a porous ceramic is applied to check the conductive substance caused by the ionized particles. By using engine and chassis dynamometer and an experiment vehicle, in which the hydrocarbon sensor (HC sensor) was exposed to the exhaust gas to create the electrical signal, the HC sensor in the exhaust line checked the conductive ions in emission gas. Generally the output electrical signal of HC sensor is followed with amount of hydrocarbon in the experiments in cold start and operation. By combining the electrical signal, a measure of conductivity of exhaust gas with hydrocarbon can be provided by OBD (On Board Diagnosis) II and EMS (Engine Management System).