This study was conducted to investigate vertical movement properties of water quality or chemical composition in three different forest stands (Pinus koraiensis, Larix leptolepis and Quercus spp. stands) in Gwangju-gun and Gyunggi-do. The results were as follows ; The pH range of precipitation was 4.62 ~ 6.72, and the average pH showed 5.74. The relationship of pH among throughfall, stemflow and precipitation showed difference of buffering capacity in tree species. According tree species, acided stemflow and alkalized stemflow had the characteristic value. In three stands, changes of the pH in early rain were larger than those of succeeding rain, except October 1998 and April 1999. Early rain influenced the cation in the acidity and concentration, but succeeding rain influenced the anion such as S $O_{4}$$^{2-}$, N $O_{3}$$^{[-10]}$ , C $l^{[-10]}$ etc. And anion components exist with gas type and minute particles, as a result, succeeding rain influenced to chemical properties by the sustaining washout.