EC(Electronic Commerce) is increasing with high speed based on the expansion of Internet. EC which is done through Internet has strong point like independence from time and space, On the contrary, it also has weak point like security problem because anybody can access easily to the system due to open network attribute of Internet. Therefore, we need the solutions that protect the security problem for safe and useful U activity, One of these solutions is the implementation of strong cipher algorithm. NPC(Non-Polynomial Complete) cipher algorithm proposed in this paper is good for the security and it overcome the limit of current 64bits cipher algorithm using 256bits key for input output and encryption key, Moreover, it is designed for the increase of calculation complexity and probability calculation by adapting more complex design for subkey generation regarded as one of important element effected to encryption.