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Photodissociation to Several Atomic Terms: Near-threshold Resonance for Production of O($^3$P) and O($^1$D) in OH Photodissociation
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  • Photodissociation to Several Atomic Terms: Near-threshold Resonance for Production of O($^3$P) and O($^1$D) in OH Photodissociation
  • Photodissociation to Several Atomic Terms: Near-threshold Resonance for Production of O($^3$P) and O($^1$D) in OH Photodissociation
저자명
이성열,Lee. Seong Yeol
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2001년|22권 12호|pp.1333-1336 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

A theoretical analysis is presented for the multichannel type resonance at energies above the dissociation threshold to O(1D) in the photodissociation of OH. Dissociations to both oxygenic terms O(3P) and O(1D) are treated. Total cross sections for producing these oxygen terms display asymmetric resonance due to the quantum interference resulting from complicated interplay of electronic states correlating to these two oxygenic terms. The branching ratios of O(3Pj, j = 0, 1, 2), and the vector properties of O(3Pj, j =0,1,2) and O(1D) display extensive changes near the threshold resonance as the result of the interactions among the electronic states correlated with O(3P) and O(1D).