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Mixed Micellization of Anionic Ammonium Dodecyl Sulfate and
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  • Mixed Micellization of Anionic Ammonium Dodecyl Sulfate and
  • Mixed Micellization of Anionic Ammonium Dodecyl Sulfate and
저자명
강계홍,김홍운,임경희,정노희,Gang. Gye Hong,Kim. Hong Un,Im. Gyeong Hui,Jeong. No Hui
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2001년|22권 9호|pp.1009-1014 (6 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

In aqueous mixtures of cationic OTAC (octadecyl trimethyl ammonium chloride) and anionic ADS (ammonium dodecyl sulfate) surfactants, mixed micelles were formed at low (< 0.2 wt %) total surfactant concentrations. For these mixtures mixed micelliza tion and interaction of surfactant molecules were examined. Mixed critical micelle concentration (CMC), thermodynamic potentials of micellization, and minimum area per surfactant molecule at the interface were obtained from surface tensiometry and electrical conductometry. The mixed micellar compositions and the estimation of interacting forces were determined on the basis of a regular solution model. The CMCs were reduced, although not substantial, and synergistic behavior of the ADS and OTAC in the mixed micelles was observed. The CMC reductions in this anionic/cationic system were comparable to those in nonionic/anionic surfactant systems. The interaction parameter $eta$ of the regular solution model was estimated to be -5 and this negative value of $eta$ indicated an overall attractive force in the mixed state.