Recently, many researches have been performed to improve the combustion and emission in a D.I.Diesel engine. Especially reduction of the soot formation in the combustion chamber is the essential to acquire the improvement of the emission performance. This emission of the diesel combustion is effected by the characteristics of air-fuel mixing. Therefore, the optical measurement technique such as LII and LIS were established in order to visualize the distribution of the soot and analyze the particle including spray in the combustion chamber. In this study, we developed the algorithm for calculating relative diameter and density of particle and applied this method to measure stimultaneously the distribution of soot and spray in a D.I. diesel engine. From this experiment we found that the soot is existed in the rich region of spray and generated caused by incapable air fuel mixture.