In this research, the goal is to ascertain the potential danger when transporting hazardous material by considering the important elements that contribute to such situation, instead of relying on the quantitative risk assessment of fixed facilities. Also, this study will verify the social and personal risk according to damage zone limits, by applying the worst case scenario and the alternative scenario that occur during the transportation process. Moreover, it has selected the optimum transportation route for maximum safety. The result of this research could be used to construct a systematic emergency system that can minimize the damage from serious industrial accidents, by effectively decreasing the danger zone and forming a connection between the community, the society, and the industries according to such evaluations.