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On the Critical Behavior of Phase Changes of a Forward-Scattered Light in a Nonpolar Binary Liquid Mixture
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  • On the Critical Behavior of Phase Changes of a Forward-Scattered Light in a Nonpolar Binary Liquid Mixture
  • On the Critical Behavior of Phase Changes of a Forward-Scattered Light in a Nonpolar Binary Liquid Mixture
저자명
Kim. Kyoung-Ran,Kang. Young-Soo,Lee. Dong-J.
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2002년|23권 12호|pp.1749-1753 (5 pages)
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대한화학회
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정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The effect of concentration fluctuations on the changes of azimuth and ellipticity are analytically obtained in a binary chiral liquid mixture, when the incident light is completely linearly polarized above (or below) the horizontal at 45°. The important results are as follows;(1) When the binary liquid is in the critical region far from the cr5itical point, the ellipticity change is proportional to isothermal compressibility factor and the fifth order of frequency and shows the logarithmic divergence. (2) In the case that the system is in the critical region far from the critical point, the azimuth change is solely due to the molecular contribution. As the system approaches to the critical point, the effect of fluctuations becomes important. If it is in the extreme close to the critical point, the term due to the concentration fluctuations is comparable to or larger than the molecular contribution

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