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Mass Spectrometric Study of Carbon Cluster Formation in Laser Ablation of Graphite at 355 nm
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  • Mass Spectrometric Study of Carbon Cluster Formation in Laser Ablation of Graphite at 355 nm
  • Mass Spectrometric Study of Carbon Cluster Formation in Laser Ablation of Graphite at 355 nm
저자명
Koo. Young-Mi,Choi. Young-Ku,Lee. Kee-Hag,Jung. Kwang-Woo
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2002년|23권 2호|pp.309-314 (6 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The ablation dynamics and cluster formation of $C_n^+$ ions ejected from 355 nm laser ablation of a graphite target in vacuum are investigated using a reflectron time-of-flight (RTOF) mass spectrometer. At low laser fluence, odd-numbered cluster ions with $3{leq}n{leq}15$ are predominantly produced. Increasing the laser fluence shifts the maximum size distribution towards small cluster ions, implying the fragmentation of larger clusters within the hot plume. The temporal evolution of $C_n^+$ ions was measured by varying the delay time of the ion extraction pulse with respect to the laser irradiation, providing significant information on the characteristics of the ablated plume. Above a laser fluence of $0.2J/cm^2$ , large cluster ions ($n{geq}30$) are produced at relatively long delay times, indicating that atoms or small carbon clusters aggregate during plume propagation. The dependence of the intensity of ablated $C_n^+$ ions on delay time after laser irradiation shows that the most probable velocity of each cluster ion decreases with cluster size.