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Dielectric Relaxation of Siloxane-Epoxy Copolymers
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  • Dielectric Relaxation of Siloxane-Epoxy Copolymers
  • Dielectric Relaxation of Siloxane-Epoxy Copolymers
저자명
Kim. Chy-Hyung,Shin. Jae-Sup
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2002년|23권 3호|pp.413-416 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The dielectric responses of 10 and 40 wt% siloxane-epoxy copolymers were investigated in temperature range near the glass transition of polydimethylsiloxane at which the dielectric transitions were also observed. On the other hand, the pure epoxy did not show any dielectric transition in measurement temperature range -90 to 150 $^{circ}C.$ The experimental data showed that for the copolymer investigated, the temperature-frequency super-position principle could be applied to the dielectric response. From the Cole-Cole equation, the dielectric relaxation of the 10 wt% siloxane near the glass transition temperature resulted in a broad distribution with ${eta}=$ 0.19 and the relaxation time at -70 $^{circ}C$ was 5.3 ${ imes}$ $10^{-2}$s. The glass transition temperature, 188 K, was estimated by using WLF relation, which was consistent with the data presented in experiment.