This paper presents a linearization technique up to the saturation region of power amplifiers. The predistorter gain polynomials which have optimum coefficients are introduced. Power amplifiers are most efficient when operated near the saturation region. Compensating the amplifier nonlinearities with these predistorter gain polynomials, the efficiency of the amplifier can be maximized. Simulation results demonstrate that the adjacent channel power ratio (ACPR) is improves by about 63 ㏈ at the band edge. The convergence and reconvergence characteristics of the linearizer are also satisfactory.