Flame behavior in inner and outer the cavity and flame temperature have an important influence on the formation and oxidation of NOx and soot. Therefore, in this study, the combustion chamber of toroidal and reentrant that have different flow characteristics of inside and outside the cavity and load, and so forth are determined as parameters of experimental conditions. An attempt has been made to obtain the effect of flame temperature and KL value in idler and outer cavity on the formation and oxidation of soot using the two-color method.